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・ Diphascon
・ Diphasiastrum
・ Diphasiastrum alpinum
・ Diphasiastrum complanatum
・ Diphasiastrum digitatum
・ Diphasiastrum sitchense
・ Diphasiastrum tristachyum
・ Diphasiastrum × issleri
・ Diphasiastrum × sabinifolium
・ Diphemanil metilsulfate
・ Diphenadione
・ Diphenhydramine
・ Diphenidine
・ Diphenidol
・ Diphenol
Diphenolic acid
・ Diphenoxylate
・ Diphenyl carbonate
・ Diphenyl diselenide
・ Diphenyl disulfide
・ Diphenyl ditelluride
・ Diphenyl ether
・ Diphenyl oxalate
・ Diphenyl sulfone
・ Diphenyl-2-pyridylmethane
・ Diphenyl-2-pyridylphosphine
・ Diphenylacetylene
・ Diphenylalanine
・ Diphenylamine
・ Diphenylamine (data page)


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Diphenolic acid : ウィキペディア英語版
Diphenolic acid

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Diphenolic acid is a carboxylic acid with molecular formula C17H18O4. Its IUPAC name is 4,4-bis(''p''-hydroxyphenyl)pentanoic acid, and it can be prepared by the condensation reaction of phenol with levulinic acid in the presence of hydrochloric acid. The equation for this synthesis is:
:2 C6H5OH + CH3C(O)CH2CH2COOH → CH3C(''p''-C6H4OH)2CH2CH2COOH + H2O
Diphenolic acid is a solid at room temperature, melting at 168–171 °C and boiling at 507 °C. According to its MSDS, diphenolic acid is soluble in ethanol, isopropanol, acetone, acetic acid, and methyl ethyl ketone, but insoluble in benzene, carbon tetrachloride, and xylene.
Diphenolic acid may be a suitable replacement for bisphenol A as a plasticizer.〔(Diphenolic acid ), National Toxicology Program〕
Diphenolate esters have been used to synthesize epoxy resins as a replacement for the digylcidyl ether of bisphenol A.The digylcidyl ethers of n-alkyl diphenolate esters have similar thermomechanical properties to the digylcidyl ether of bisphenol A when cured, but the viscosity and glass transition temperature vary as a function of the ester length.〔Maiorana, A., Spinella, S., Gross, R.A., Biomacromolecules, 2015, doi 10.1021 ()〕 Diphenolate esters have also been used to synthesize polycarbonates with a potential for water solubility.〔Ruifeng Zhang and J. A. Moore, Macromolecular Symposia,199 (Polycondensation 2002), 375-390 (2003)〕
==References==


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